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CHEMISTRY FORM 2


1. STRUCTURE OF THE ATOM, AND THE PERIODIC TABLE
2. CHEMICAL FAMILIES AND PATTERNS IN PROPERTIES
3. CHEMICAL BONDING AND STRUCTURE
4. SALTS
5. EFFECT OF AN ELECTRIC CURRENT ON SUBSTANCES
6. CARBON AND SOME OF ITS COMPOUNDS
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Effect of an electric current on substances: Electrical conductivity of molten substances

5.0 Effect of an electric current on substances


5.2 Electrical conductivity of molten substances

Observe conduction of electricity by molten lead (II) bromide (PbBr2).


(courtesy Youtube-The electrolysis of lead bromide by David Read)

Questions 5.2

  1. What type of bond exists between lead and bromine in solid lead (II) bromide?

  2. What is the structure of lead (II) bromide? Explain.

  3. Write the formulae of lead (II) ions and bromide ions, indicating their state symbols when molten.

  4. Which ions move to the anode and which ones move to the cathode?

  5. Explain why lead (II) bromide conducts electricity in molten state but not in solid state.

  6. Which of the following substances are also expected to conduct electricity in molten state but not as solids: H2O, NaCl, CS2, CuO, NH3, SiO2, Al2O3, PbI2?


Answers to Questions 5.2


Ionic compounds conduct electricity in molten state because the ionic bonds are broken, setting the ions free to move about. We say the ions are dissociated. In solid state, the ions are held together by strong ionic bonds; so they are not free to move about and conduct electricity. We can use this fact to identify ionic compounds.