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CHEMISTRY FORM 2


1. STRUCTURE OF THE ATOM, AND THE PERIODIC TABLE
2. CHEMICAL FAMILIES AND PATTERNS IN PROPERTIES
3. CHEMICAL BONDING AND STRUCTURE
4. SALTS
5. EFFECT OF AN ELECTRIC CURRENT ON SUBSTANCES
6. CARBON AND SOME OF ITS COMPOUNDS
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Salts: Reacting an Acid with a Carbonate (or hydrogencarbonate of metal)

4.0 Salts


4.4.3 Reacting an Acid with a Carbonate (or hydrogencarbonate of metal)


Observe the video showing preparation of salts from acids and carbonates.


Questions 4.4.3

You are required to prepare copper (II) chloride crystals by reacting a suitable acid with a carbonate. Explain how you would go about this. Include an equation for the reaction. Describe the observations made during the reaction.


Answers to Questions 4.4.3


Except for the carbonates of sodium, potassium and ammonium ions, the state symbol of carbonates is (s) because they are insoluble. The hydrogencarbonates react in a similar way; but their state symbol is (aq) because they are soluble. Figure 4.4.3 shows the appearance of copper (II) chloride.


Copper (II) chloride crystals, Chemistry, high school chemistry

Figure 4.4.3(a) Copper (II) chloride crystals


Hydrated salts

Most of the salts that crystallyze do so by combining with some definite amount of water, called water of crystallization. Copper (II) sulphate, for example, crystalizes with 5 molecules of water. The formula of hydrated copper (II) sulphate is therefore CuSO4.5H2O. Table 4.4.3 shows more examples of hydrated salts and the number of molecules of water involved.


Hydrated salts, Chemistry

Figure 4.4.3(b) Hydrated salts


Some anhydrous salts slowly absorb water vapour from the air and become hydrated. They are called hygroscopic salts. An example is anhydrous copper (II) sulphate. Others absorb so much water and turn into solution when exposed to air. They are called deliquescent salts. An example is iron (III) chloride.


Still others lose water of crystallization and are called efflorescent salts. Hydrated sodium carbonate is an example. Efflorescent salts normally burst plastic bottles open or slowly overflow under the lid because of this.